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negative thermal expansion : ウィキペディア英語版
negative thermal expansion
Negative thermal expansion is a physicochemical process in which some materials contract upon heating rather than expand as most materials do. Materials which undergo this unusual process have a range of potential engineering, photonic, electronic, and structural applications. For example, if one were to mix a negative thermal expansion material with a "normal" material which expands on heating, it could be possible to make a zero expansion composite material.
== Origin of negative thermal expansion ==

There are a number of physical processes which may cause contraction with increasing temperature, including transverse vibrational modes, Rigid Unit Modes and phase transitions.
Recently, Liu et al. showed that the NTE phenomenon originates from the existence of high pressure, small volume phases with higher entropy, with their configurations present in the stable phase matrix through thermal fluctuations.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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